Solvation-Driven Charge Transfer and Localization in Metal Complexes
نویسندگان
چکیده
منابع مشابه
Solvation-Driven Charge Transfer and Localization in Metal Complexes
In any physicochemical process in liquids, the dynamical response of the solvent to the solutes out of equilibrium plays a crucial role in the rates and products: the solvent molecules react to the changes in volume and electron density of the solutes to minimize the free energy of the solution, thus modulating the activation barriers and stabilizing (or destabilizing) intermediate states. In c...
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ژورنال
عنوان ژورنال: Accounts of Chemical Research
سال: 2015
ISSN: 0001-4842,1520-4898
DOI: 10.1021/ar5003939